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mLLDPE-NA1Category I

mLLDPE (Metallocene LLDPE)

Metallocene Linear Low-Density Polyethylene produced with single-site catalyst technology for narrow molecular-weight distribution and uniform comonomer placement. Provides high puncture and dart-drop resistance, high tensile strength at reduced film gauges, low-haze optical clarity, and consistent hot-tack performance — enabling 15–30% down-gauging in stretch hood, lamination, frozen-food and high-performance flexible packaging films.

Polyethylene FDA REACH TDS SDS

Logistics & Documentation

Plastic-Pallet Option · Import Documentation Support

  • Lead Time: Depends on supplier availability, production schedule, shipping route and destination. Lead time and dispatch are confirmed with each quotation rather than published as a fixed figure.
  • Packaging Option: Injection-molded plastic pallets available on request as an alternative to wooden pallets, subject to supplier capability and order size.
  • Documentation Support: Import documentation support available. Available documents may include TDS, SDS, COA, origin documents and compliance declarations where applicable.
mLLDPE (Metallocene LLDPE) — category illustration
Category illustration — actual product appearance may vary by grade and batch.

Technical & commercial reference

Metallocene LLDPE (mLLDPE) — how buyers specify and compare offers

mLLDPE is specified by melt index, density and comonomer type. Those three values, plus the layer the resin will run in, determine whether an offer is usable.

Applications

Where it is used

  • Stretch and cling film where puncture resistance and holding force matter
  • Lamination and sealant layers requiring a low seal initiation temperature
  • Heavy-duty shipping sacks
  • Blends with conventional LLDPE or LDPE to lift toughness

Selection

How the right grade is chosen

  • Melt index against the extruder and die design of the line
  • Density, which drives stiffness, clarity and seal behaviour
  • Comonomer (hexene or octene) — it changes toughness and tear balance
  • Seal initiation temperature where fast packaging lines are involved
  • Slip and antiblock package, since additive-free grades handle differently

Specification

What to state in the enquiry

  • Melt index with the test condition stated
  • Density and comonomer type
  • Additive package present or absent in the offered grade
  • Optical properties where clarity is required

Procurement

Sourcing considerations

  • Give the film structure, layer and line type in the enquiry rather than only the resin family
  • Ask for the TDS of the offered grade and a batch COA
  • Resin substitutions normally require a line trial before qualification
  • Grade, specification, documentation, packaging, availability and delivery terms are confirmed against supplier documentation with each quotation.

Comparison

Comparing competing offers

  • Performance per micron of film at equal output, not price per kilogram alone
  • Consistency of melt index between lots
  • Additive package match to the existing formulation

General industry guidance. Grade, specification, documentation, packaging and delivery terms for mLLDPE (Metallocene LLDPE) are confirmed against supplier documentation with each quotation. Request a quotation.

About this product

mLLDPE (Metallocene LLDPE) — product overview

mLLDPE-NA1 is metallocene linear low-density polyethylene produced on a single-site catalyst platform, of North American origin. The single-site catalyst delivers a narrow molecular-weight distribution and uniform comonomer placement, translating into higher puncture and dart-drop resistance, higher tensile strength at reduced film gauge, sharper optical clarity and stronger hot-tack than conventional Ziegler-Natta LLDPE. Together those properties support real-world down-gauging in stretch-hood, lamination, frozen-food and premium flexible-packaging films — the typical commercial reason converters switch. Because rheology differs materially from conventional LLDPE, film-line adjustments (screw profile, die gap, BUR) are usually required on first run. Origin, catalyst-family confirmation, resin datasheet and MFI are confirmed against the shipped lot.

Document & COA status
  • • TDS: Displayed properties are an Allzone technical reference; manufacturer documentation is available on request.
  • • SDS: Safety data is subject to grade and supplier confirmation. One SDS does not necessarily apply to every grade or supplier.
  • • COA: Certificate of Analysis is provided against the confirmed shipment, grade and batch. No stock, lead-time or regulatory claim is implied without written confirmation.

Technical Data Sheet

TDS · mLLDPE-NA1

Product form

Pellets (cylindrical, 2–4 mm)

Appearance

White

Carrier / matrix

North American Origin | Single-Site Metallocene Catalyst

Key Physical & Chemical Properties

Active concentrate20 – 40 %
Bulk density0.95 – 1.10 g/cm³
MFI (190 °C / 2.16 kg)2 – 8 g/10 min
Limiting Oxygen Index (LOI)n/a
Smoke density (ASTM E662)n/a
UV resistancen/a

Recommended dosage

2.0 – 5.0 % depending on requirement.

Processing temperature

180 – 220 °C

Packaging

25 kg multi-wall poly-woven bag with PE inner liner, 1000 kg FIBC, or 25 MT FCL bulk.

Shelf life

24 months from production date in unopened original packaging.

Storage

Store dry below 35 °C, away from direct sunlight, ignition sources and incompatible chemicals.

Target Applications

  • Greenhouse anti-fog / anti-IR films
  • Agricultural mulch and silage films
  • LSZH wire & cable jacketing
  • Telecommunication & data cable insulation

Key Features

  • Zero halogen, low smoke, low toxicity emission
  • Anti-fog active for 12+ growing cycles
  • Excellent dispersion in PE / EVA matrices
  • REACH compliant additive package

Safety Data Sheet · GHS / OSHA HazCom / WHMIS 2015

SDS · mLLDPE-NA1

Signal word

Not classified

Not classified as hazardous under OSHA HazCom 2012 / GHS / WHMIS 2015.

§ 1Identification
▾
Product code
mLLDPE-NA1
Product name
mLLDPE (Metallocene LLDPE)
Product use
Industrial raw material — Blown Film Packaging, Agricultural Liners, Food & Livestock Feed.
Restrictions
Industrial use only. Not for direct consumer sale unless explicitly labelled food/feed grade.
Supplier
Allzone Trading Corp.
Address
Ontario, Canada
Technical contact
technical@allzonetrading.ca · +1 (437) 297-6255
Emergency
CHEMTREC +1 800 424 9300 / CANUTEC +1 613 996 6666
§ 2Hazards Identification
▾
GHS classification
Not classified as hazardous under OSHA HazCom 2012 / GHS / WHMIS 2015.
Signal word
Not classified
Pictograms
None required.
Hazard statements
No GHS hazard statements apply to this article in supplied form.
Precautionary statements
P210 Keep away from heat, sparks, open flames and hot surfaces.
§ 3Composition / Information on Ingredients
▾
Mixture
Engineered polyethylene based mlldpe (metallocene lldpe).
Carrier
North American Origin | Single-Site Metallocene Catalyst
§ 4First Aid Measures
▾
Inhalation
Move to fresh air. Get medical advice if discomfort persists.
Skin contact
Wash with soap and water. Get medical advice if irritation persists.
Eye contact
Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
Ingestion
Rinse mouth. Do not induce vomiting. Seek medical advice if discomfort persists.
Hot melt burns
For pellet-form products processed at melt temperature: cool affected area with cold water. Do NOT peel solidified polymer from skin — seek medical attention.
§ 5Fire-Fighting Measures
▾
Suitable extinguishing media
Water spray, dry chemical, CO2, foam.
Unsuitable media
None known.
Special hazards
Combustion may produce CO, CO2 and dense black smoke. Polymer melt drips during fire.
PPE for firefighters
Self-contained breathing apparatus (SCBA) and full protective gear.
§ 6Accidental Release Measures
▾
Personal precautions
Wear PPE per Section 8. Avoid generating dust. Ventilate area.
Environmental precautions
Prevent entry into drains, waterways or soil. Notify authorities if significant release.
Cleanup
Sweep or vacuum spilled material into labelled container for recycling or disposal.
§ 7Handling & Storage
▾
Handling
Handle in well-ventilated areas. Avoid generating dust. Use appropriate PPE.
Storage
Store dry below 35 °C, away from direct sunlight and ignition sources.
Incompatible materials
Strong oxidizers.
§ 8Exposure Controls / Personal Protection
▾
Engineering controls
Local exhaust ventilation at material transfer and melt-processing points. Maintain dust below regional OEL.
Respiratory protection
Dust mask if fines / dust generated.
Hand protection
Heat-resistant gloves when handling molten polymer; cotton gloves for cold pellets.
Eye protection
Safety glasses with side shields; chemical splash goggles when handling powders or molten material.
Body protection
Long-sleeve work clothing. Full chemical apron for corrosive products.
Exposure limits
Follow nuisance-dust limits (10 mg/m³ total, 5 mg/m³ respirable).
§ 9Physical & Chemical Properties
▾
Physical state
Solid pellets / powder
Color
White / off-white / pre-colored
Odor
Odorless to faint polymer odor
pH (1 % solution)
Not applicable (insoluble)
Melting / decomposition
Polymer melt 110 – 250 °C (matrix dependent)
Flash point
Not applicable (solid article)
Solubility (water)
Insoluble
Density
0.9 – 2.2 g/cm³ depending on grade
§ 10Stability & Reactivity
▾
Stability
Stable under normal storage and handling conditions.
Conditions to avoid
Excessive heat, ignition sources, prolonged UV exposure.
Hazardous decomposition products
CO, CO2, polymer fragment volatiles. Azodicarbonamide additionally releases NH3, N2.
§ 11Toxicological Information
▾
Acute oral toxicity (LD50, rat)
Not classified (> 2000 mg/kg expected)
Skin irritation
Not classified for solid article in supplied form.
Eye irritation
Mechanical irritation possible from dust.
Respiratory sensitization
Not classified.
Carcinogenicity
Not classified.
Mutagenicity / reproductive tox.
No known effects based on current data.
§ 12Ecological Information
▾
Aquatic toxicity
Not classified — substance is essentially inert in water.
Persistence
Persistent in environment — polymer fragments are not readily biodegradable.
Bioaccumulation
No bioaccumulation potential expected.
§ 13Disposal Considerations
▾
Product disposal
Dispose in accordance with local, provincial, state and federal regulations. Recycle polymer fractions through certified plastic recyclers where possible.
Packaging disposal
Recycle empty bags / liners after thorough emptying.
Waste codes
Non-hazardous solid waste (EWC 07 02 13 typical).
§ 14Transport Information
▾
Status
Not regulated for transport under DOT / IATA / IMDG / ADR / TDG.
§ 15Regulatory Information
▾
REACH (EC 1907/2006)
All components registered or exempt. No SVHC listed above 0.1 % w/w.
RoHS (EU 2011/65)
Heavy metals < 1000 ppm (Pb, Hg, Cr⁶⁺) and < 100 ppm (Cd).
Food contact
Complies with FDA 21 CFR 178.3297 (colorants for polymers) where applicable.
WHMIS 2015 (Canada)
Not classified as a hazardous product.
TSCA / DSL
All substances listed on US TSCA and Canadian DSL inventories.
§ 16Other Information
▾
Revision
Rev. 2026-06-15 (representative industry-standard datasheet).
Disclaimer
Information provided in good faith based on current knowledge. No warranty expressed or implied. User is responsible for verifying suitability for end use and compliance with local regulations.
Document
SDS for mLLDPE-NA1

This SDS is provided as representative industry-standard guidance. For project-specific binding documentation, please request the formal current revision via the technical contact above.

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