A-FRCategory D

Flame Retardant (FR) Masterbatch

Halogenated and Halogen-Free (HFFR) configurations meeting UL-94 V-0, V-1 and V-2 structural safety ratings.

Polyethylene RoHS REACH TDS SDS

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Logistics & Documentation

Plastic-Pallet Option · Import Documentation Support

Lead Time: Depends on supplier stock, production schedule, shipping route and destination. GTA dispatch typically targets 24–48 hours on confirmed stock items.
Packaging Option: Injection-molded plastic pallets available on request as an alternative to wooden pallets, subject to supplier capability and order size.
Documentation Support: Import documentation support available. Available documents may include TDS, SDS, COA, origin documents and compliance declarations where applicable.

Additive identity

Values below are taken from the product record or the supplier technical data sheet held on file. Anything not shown here is confirmed in writing at quotation.

Delivery form: Masterbatch
Compatible polymers: Polyethylene
Regulatory status: RoHS, REACH

Additive family

Flame Retardant (FR) Masterbatch is supplied under this additive family — compare the full family before fixing on a grade.

Flame Retardants

Flame Retardant (FR) Masterbatch — category illustration — Category illustration — actual product appearance may vary by grade and batch.

About this product

Flame Retardant (FR) Masterbatch — product overview

A-FR is Allzone's flame-retardant masterbatch programme for polyolefin compounds used in wire & cable jackets and construction plastics. The product is offered in both halogenated and halogen-free (HFFR) chemistries so buyers can match the retardant system to their fire-safety target and regulatory scope. UL-94 ratings (V-0, V-1, V-2) achievable in a given formulation depend on base resin, part geometry, wall thickness, additive interaction and processing conditions — target rating must be validated on the customer's own part, not assumed from the masterbatch alone. Halogen chemistry is generally lower cost with higher loading efficiency; HFFR chemistry is preferred where smoke toxicity, corrosive by-products or environmental regulation drive the decision. Specific grade, addition rate and letdown ratio are confirmed at RFQ, together with the manufacturer TDS/SDS relevant to the selected chemistry.

Document & COA status

• TDS: Displayed properties are an Allzone technical reference; manufacturer documentation is available on request.
• SDS: Safety data is subject to grade and supplier confirmation. One SDS does not necessarily apply to every grade or supplier.
• COA: Certificate of Analysis is provided against the confirmed shipment, grade and batch. No stock, lead-time or regulatory claim is implied without written confirmation.

Technical Data Sheet

TDS · A-FR

Product form

Pellets (cylindrical, 2–4 mm)

Appearance

White

Carrier / matrix

Polyethylene compatible base resin

Key Physical & Chemical Properties

Active ingredient	20 – 40 % concentrate
Bulk density	0.95 – 1.10 g/cm³
Melt Flow Index (190 °C / 2.16 kg)	5 – 12 g/10 min
Moisture content	≤ 0.10 %
Recommended let-down ratio	1 : 50 to 1 : 200

Recommended dosage

0.5 – 3.0 % by weight depending on target performance.

Processing temperature

190 – 260 °C

Packaging

25 kg multi-wall poly-woven bag with PE inner liner, 1000 kg FIBC, or 25 MT FCL bulk.

Shelf life

24 months from production date in unopened original packaging.

Storage

Store dry below 35 °C, away from direct sunlight, ignition sources and incompatible chemicals.

Target Applications

Blown / cast film and lamination
Injection molding of automotive and consumer parts
Pipe, sheet, and profile extrusion
Wire & cable jacketing where applicable

Key Features

Long-lasting performance with low dosage
Compatible with most polyolefin and engineering resins
Excellent dispersion — no agglomerates
REACH-registered active components

Safety Data Sheet · GHS / OSHA HazCom / WHMIS 2015

SDS · A-FR

Signal word

Not classified

Not classified as hazardous under OSHA HazCom 2012 / GHS / WHMIS 2015.

§ 1Identification

▾

Product code: A-FR
Product name: Flame Retardant (FR) Masterbatch
Product use: Industrial raw material — Wire & Cable, Building & Construction.
Restrictions: Industrial use only. Not for direct consumer sale unless explicitly labelled food/feed grade.
Supplier: Allzone Trading Corp.
Address: Ontario, Canada
Technical contact: technical@allzonetrading.ca · +1 (437) 297-6255
Emergency: CHEMTREC +1 800 424 9300 / CANUTEC +1 613 996 6666

§ 2Hazards Identification

▾

GHS classification: Not classified as hazardous under OSHA HazCom 2012 / GHS / WHMIS 2015.
Signal word: Not classified
Pictograms: None required.
Hazard statements: No GHS hazard statements apply to this article in supplied form.
Precautionary statements: P210 Keep away from heat, sparks, open flames and hot surfaces.

§ 3Composition / Information on Ingredients

▾

Mixture: Engineered polyethylene based flame retardant (fr) masterbatch.
Carrier: Polyethylene compatible polymer.

§ 4First Aid Measures

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Inhalation: Move to fresh air. Get medical advice if discomfort persists.
Skin contact: Wash with soap and water. Get medical advice if irritation persists.
Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do.
Ingestion: Rinse mouth. Do not induce vomiting. Seek medical advice if discomfort persists.
Hot melt burns: For pellet-form products processed at melt temperature: cool affected area with cold water. Do NOT peel solidified polymer from skin — seek medical attention.

§ 5Fire-Fighting Measures

▾

Suitable extinguishing media: Water spray, dry chemical, CO2, foam.
Unsuitable media: None known.
Special hazards: Combustion may produce CO, CO2 and dense black smoke. Polymer melt drips during fire.
PPE for firefighters: Self-contained breathing apparatus (SCBA) and full protective gear.

§ 6Accidental Release Measures

▾

Personal precautions: Wear PPE per Section 8. Avoid generating dust. Ventilate area.
Environmental precautions: Prevent entry into drains, waterways or soil. Notify authorities if significant release.
Cleanup: Sweep or vacuum spilled material into labelled container for recycling or disposal.

§ 7Handling & Storage

▾

Handling: Handle in well-ventilated areas. Avoid generating dust. Use appropriate PPE.
Storage: Store dry below 35 °C, away from direct sunlight and ignition sources.
Incompatible materials: Strong oxidizers.

§ 8Exposure Controls / Personal Protection

▾

Engineering controls: Local exhaust ventilation at material transfer and melt-processing points. Maintain dust below regional OEL.
Respiratory protection: Dust mask if fines / dust generated.
Hand protection: Heat-resistant gloves when handling molten polymer; cotton gloves for cold pellets.
Eye protection: Safety glasses with side shields; chemical splash goggles when handling powders or molten material.
Body protection: Long-sleeve work clothing. Full chemical apron for corrosive products.
Exposure limits: Follow nuisance-dust limits (10 mg/m³ total, 5 mg/m³ respirable).

§ 9Physical & Chemical Properties

▾

Physical state: Solid pellets / powder
Color: White / off-white / pre-colored
Odor: Odorless to faint polymer odor
pH (1 % solution): Not applicable (insoluble)
Melting / decomposition: Polymer melt 110 – 250 °C (matrix dependent)
Flash point: Not applicable (solid article)
Solubility (water): Insoluble
Density: 0.9 – 2.2 g/cm³ depending on grade

§ 10Stability & Reactivity

▾

Stability: Stable under normal storage and handling conditions.
Conditions to avoid: Excessive heat, ignition sources, prolonged UV exposure.
Hazardous decomposition products: CO, CO2, polymer fragment volatiles. Azodicarbonamide additionally releases NH3, N2.

§ 11Toxicological Information

▾

Acute oral toxicity (LD50, rat): Not classified (> 2000 mg/kg expected)
Skin irritation: Not classified for solid article in supplied form.
Eye irritation: Mechanical irritation possible from dust.
Respiratory sensitization: Not classified.
Carcinogenicity: Not classified.
Mutagenicity / reproductive tox.: No known effects based on current data.

§ 12Ecological Information

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Aquatic toxicity: Not classified — substance is essentially inert in water.
Persistence: Persistent in environment — polymer fragments are not readily biodegradable.
Bioaccumulation: No bioaccumulation potential expected.

§ 13Disposal Considerations

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Product disposal: Dispose in accordance with local, provincial, state and federal regulations. Recycle polymer fractions through certified plastic recyclers where possible.
Packaging disposal: Recycle empty bags / liners after thorough emptying.
Waste codes: Non-hazardous solid waste (EWC 07 02 13 typical).

§ 14Transport Information

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Status: Not regulated for transport under DOT / IATA / IMDG / ADR / TDG.

§ 15Regulatory Information

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REACH (EC 1907/2006): All components registered or exempt. No SVHC listed above 0.1 % w/w.
RoHS (EU 2011/65): Heavy metals < 1000 ppm (Pb, Hg, Cr⁶⁺) and < 100 ppm (Cd).
Food contact: Not intended for food-contact applications.
WHMIS 2015 (Canada): Not classified as a hazardous product.
TSCA / DSL: All substances listed on US TSCA and Canadian DSL inventories.

§ 16Other Information

▾

Revision: Rev. 2026-06-15 (representative industry-standard datasheet).
Disclaimer: Information provided in good faith based on current knowledge. No warranty expressed or implied. User is responsible for verifying suitability for end use and compliance with local regulations.
Document: SDS for A-FR

This SDS is provided as representative industry-standard guidance. For project-specific binding documentation, please request the formal current revision via the technical contact above.

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